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Chapter 21: 12P (page 817)

What reagents are needed to convert each compound into butanal (CH3CH2CH2CHO )?

a.

b.

c.

Short Answer

Expert verified

a)

b)

c)

Step by step solution

01

Gilman’s reagent

Gilman’s reagent is used to form carbon-carbon bonds in organic reactions or synthesis.

02

Formation of the product

a)

The reaction of benzene with acetyl chloride in the presence of aluminum trichloride gives acetophenone.

The reaction is shown below.

Synthesis in a

b)

The reaction of benzoyl chloride with Gilman’s reagent in the presence of water gives acetophenone.

The reaction is shown below.

Synthesis in b

c)

The reaction of ethynylbenzene water in the presence of sulfuric acid and mercuric sulfate gives acetophenone.

The reaction is shown below.

Synthesis in c

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Most popular questions from this chapter

Which carbonyl group in each pair absorbs at a higher frequency?

a.

b.

What carbonyl compound and amine are formed by the hydrolysis of each compound?

a.

b.

c.

Draw the products of each reaction.

a.

b.

Devise a synthesis of each alkene using a Wittig reaction to form the double bond. You may use benzene and organic alcohols having four or fewer carbons as starting materials and any required reagents

a.

b.

Label each compound as an acetal, a hemiacetal, or an ether.

a.

b.

c.

d.
See all solutions

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