Chapter 21: 29P (page 817)
Draw the products of each reaction.
a.
b.
Short Answer
a.
b.
Chapter 21: 29P (page 817)
Draw the products of each reaction.
a.
b.
a.
b.
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Get started for freeGive the IUPAC name (including any E,Z designation) for each unsaturated aldehyde. Neral is obtained from lemon grass, and cucumber aldehyde (Problem 1.30) contributes to the aroma of a fresh mango.
a.
b.
Draw a stepwise mechanism for the following reaction, a key step in the synthesis of the anti-inflammatory drug celecoxib (trade name Celebrex).
Although the carbonyl absorption of cyclic ketones generally shifts to higher wavenumber with decreasing ring size, C=O of cyclopropenone absorbs at lower wavenumber in its roman IR spectrum than the C=O of cyclohex-2-enone. Explain this observation by using the principles of aromaticity learned in Chapter 17.
a. How many stereogenic centers are present in -D-galactose?
b. Label the hemiacetal carbon in -D-galactose.
c. Draw the structure of -D-galactose.
d. Draw the structure of the polyhydroxy aldehyde that cyclizes to - and
-D-galactose.
e. From what you learned in Section 21.16B, what product (s) is (are) formed
when -D-galactose is treated with CH3OH and an acid catalyst?
Label each compound as an acetal, a hemiacetal, or an ether.
a.
b.
c.
d.
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