Chapter 21: 46P (page 817)
Draw the products of each reaction.
a.
b.
c.
d.
e.
f.
g.
h.
Short Answer
a.
b.
c.
d.
e.
f.
g.
h.
Chapter 21: 46P (page 817)
Draw the products of each reaction.
a.
b.
c.
d.
e.
f.
g.
h.
a.
b.
c.
d.
e.
f.
g.
h.
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Get started for freeWhat two enamines are formed when 2-methylcyclohexanone is treated with (CH3)2NH?
Give the structure corresponding to each name.
a. 2-methyl-3-phenylbutanal
b. 3,3-dimethylcyclohexanecarbaldehyde
c. 3-benzoylcyclopentanone
d. 2-formylcyclopentanone
e. (R)-3-methylheptan-2-one
f. m-acetylbenzaldehyde
g. 2-sec-butylcyclopent-3-enone
h. 5,6-dimethylcyclohex-1-enecarbaldehyde
-d-Glucose, a hemiacetal, can be converted to a mixture of acetals on treatment with in the presence of acid. Draw a stepwise mechanism for this reaction. Explain why two acetals are formed from a single starting material.
Etoposide, sold as a phosphate derivative with the trade name of Etopophos, is used for the treatment of lung cancer, testicular cancer, and lymphomas. (a) Locate the acetals in etoposide. (b) What products are formed when all of the acetals are hydrolyzed with aqueous acid?
Outline a synthesis of each Wittig reagent from Ph3P and an alkyl halide.
a.
b.
c.
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