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Chapter 29: Q39P (page 1192)

Draw the organic products formed in each reaction

Short Answer

Expert verified

Chemical reactions comprising organic compounds are termed organic reactions. Several new organic molecules can be created using organic reactions.

A few examples of organic reactions include addition reactions and elimination reactions.

Step by step solution

01

Organic reactions

Chemical reactions comprising organic compounds are termed organic reactions. Several new organic molecules can be created using organic reactions.

A few examples of organic reactions include addition reactions and elimination reactions.

02

Synthesis of amino acids

Numerous ways are employed to create amino acids in the laboratory. The combination of an -halo acids with ammonia can generate amino acid. Malonic ester synthesis can also be employed to generate amino acids.

03

Predicting the products of various reactions

a. The reaction of the given -halo carboxylic acid with excess ammonia leads to the formation of an amine. The reaction can be given as:

b. The given reaction is the alkylation of diethyl acetamidomalonate derivative leading to the formation of amino acid. The reaction can be given as:

c.The given reaction is Strecker synthesis, and the conversion of aldehyde to amino acid happens in this reaction. The aldehyde reacts with and NaCN to form -amino nitrile. This is hydrolyzed in aqueous acid to an amino acid.

The reaction can be given as:

d. The given reaction involves the synthesis of amino acids from diethyl acetamidomalonate. The reaction can be given as:

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Most popular questions from this chapter

Use the given experimental data to deduce the sequence of an octapeptide that contains the following amino acids: Ala, Gly (2 equiv), His (2 equiv), Ile, Leu and Phe. Edman degradation cleaves Gly from the octapeptide, and carboxypeptidase forms Leu and a heptapeptide. Partial hydrolysis forms the following fragments: Ile-His-Leu, Gly, Gly-Ala-Phe-His, and Phe-His-Ile.

What amino acid is formed when CH3CONHCH(CO2Et)2is treated with the following series of reagents:

Consider two molecules of a tetrapeptide composed of only alanine residues. Draw the hydrogen bonding interactions that result when these two peptides adopt a parallel β-pleated sheet arrangement. Answer this same question for the antiparallel β-pleated sheet arrangement.

L-thyroxine, a thyroid hormone and oral medication used to treat thyroid hormone deficiency, is an amino acid that does not exist in proteins. Draw the zwitterionic form of L-thyroxine.

Explain why the pKaof the -NH3+group of an α-amino acid is lower than the pKaof the ammonium ion derived from a 1°amine (RNH3+). For example, pKaof the -NH3+group of alanine is 9.87 but the pKaof CH3NH3+is 10.63.

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