Chapter 31: Question 31.1 (page 1233)
One component of jojoba oil is a wax formed from eicosenoic acid and . Draw the structure of the wax, including the cis geometry of both carbon-carbon double bonds.
Short Answer
Answer
Chapter 31: Question 31.1 (page 1233)
One component of jojoba oil is a wax formed from eicosenoic acid and . Draw the structure of the wax, including the cis geometry of both carbon-carbon double bonds.
Answer
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Get started for freeA difficult problem in the synthesis of PGFis the introduction of the OH group at C15 in the desired configuration.
A well known synthesis of PGFinvolves reaction of A with (a metal hydride reagent similar in reactivity to, to form two isomeric products, B and C. Draw their structures and indicate their stereochemical relationship.
Suggest a reagent to convert A to the single stereoisomer X.
Phosphoacylglycerols should remind you of soaps (Section 3.6). In what ways are these compounds similar?
Classify each terpene and terpenoid in Problem 31.26 (e.g., as a monoterpene, sesquiterpene, etc.).
Betamethasone is a synthetic anti-inflammatory steroid used as a topical cream for itching. Betamethasone is derived from cortisol, with the following structural additions: a C=C between C1 and C2, a fluorine at C9, and a methyl group at C16. The configuration at C9 is R, and the configuration at C16 is S. Draw the structure of betamethasone.
Crocin, which occurs naturally in crocus and gardenia flowers, is primarily responsible for the color of saffron.
(a) What lipid and monosaccharides are formed by the hydrolysis of crocin?
(b) Classify the lipid as a monoterpenoid, diperpenoid, etc., and locate the isoprene units.
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