Chapter 13: Q 26. (page 521)
Question:Which compound gives a molecular ion at m/z= 122: , , or ?
Short Answer
Answer
, Molecular ion peak atm/z = 122
Chapter 13: Q 26. (page 521)
Question:Which compound gives a molecular ion at m/z= 122: , , or ?
Answer
, Molecular ion peak atm/z = 122
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Get started for freeQuestion:Suppose you have two bottles, labeled ketone A and ketone B. You know that one bottle contains and one contains but you do not know which ketone is in which bottle. Ketone A gives a fragment at m/z= 99 and ketone B givesa fragment at m/z= 113. What are the likely structures of ketones A and B from these fragmentation data?
Question: Which of the following has higher energy:
(a) IR light of 3000 or 1500 in wavenumber;
(b) IR light having a wavelength of 10 µm or 20 µm?
Question:A low-resolution mass spectrum of the neurotransmitter dopamine gave a molecular ion at m/z= 153. Two possible molecular formulas for this molecular ion are and . A high-resolution mass spectrum provided an exact mass at 153.0680. Which of the possible molecular formulas is the correct one?
Question: Explain why a ketone carbonyl typically absorbs at a lower wavenumber than an aldehyde carbonyl (1715 vs. 1730cm-1)
Question: What are the major IR absorptions in the functional group region for each compound?
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