Chapter 13: Q 26. (page 521)
Question:Which compound gives a molecular ion at m/z= 122: , , or ?
Short Answer
Answer

, Molecular ion peak atm/z = 122
Chapter 13: Q 26. (page 521)
Question:Which compound gives a molecular ion at m/z= 122: , , or ?
Answer

, Molecular ion peak atm/z = 122
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Question: Propose structures consistent with each set of data: (a) a hydrocarbon with a molecular ion at m/z = 68 and IR absorptions at 3310, 3000–2850, and 2120 ;
(b) a compound containing C, H, and O with a molecular ion at m/z = 60 and IR absorptions at 3600–3200 and 3000–2850 .
Question: How would each of the following pairs of compounds differ in their IR spectra?

Question: Treatment of anisole with and forms P, which has peaks in its mass spectrum at m/z = 142 (M), 144 (M + 2), 129, and 127. P has absorptions in its IR spectrum at 3096–2837 (several peaks), 1582, and 1494 cm–1. Propose possible structures for P.
Question: The mass spectrum of the following compound shows fragments at m/z = 127, 113, and 85. Propose structures for the ions that give rise to these peaks.

Question: What is the mass of the molecular ion formed from compounds having each molecular formula:
(a) ; (b);(c); (d) methamphetamine ?
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