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Chapter 18: 37 P (page 721)

Draw the products formed when each compound is treated with ${CH}_{3} {CH}_{2} COCl, {AlCl}_{3}$

Short Answer

Expert verified

a. No reaction

b. No reaction

c.

Step by step solution

01

Friedel-Craft acylation reaction

Treatment of substituted benzene with RCOCl in the presence of the aluminum trichloride results in substitution in the aromatic ring.

02

Product formation in a, b, and c

a. 2-Methyl-1-phenylpropan-1-one does not react with ${CH}_{3} {CH}_{2} COCl, {AlCl}_{3}$ .

b. N, N-Dimethylaniline does not react with ${CH}_{3} {CH}_{2} COCl, {AlCl}_{3}$ .

c. The reaction of N-phenylacetamide with ${CH}_{3} {CH}_{2} COCl, {AlCl}_{3}$ is shown below.

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Most popular questions from this chapter

Question: Devise a synthesis of optically active (S)-fluoxetine (trade name Prozac) from the given starting materials and any other needed reagents.

Draw the products formed when each compound is treated with ${HNO}_{3}$ and $H_{2} {SO}_{4}$ .

Intramolecular reactions are also observed in Friedel–Crafts alkylation. Draw the intramolecular alkylation product formed from each of the following reactants. (Watch out for rearrangements!)

Which of the following compounds undergo Friedel–Crafts alkylation with ${CH}_{3} Cl$ and ${AlCl}_{3}$ ? Draw the products formed when a reaction occurs.

Why is benzene less reactive toward electrophiles than an alkene, even though it has more π electrons than an alkene (six versus two)?

See all solutions

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