Question: Give IUPAC name of each compound.

a.

b.

c.

d.

Short Answer

Expert verified

Answer

The IUPAC names of given compounds are as follows:

  1. 4-tert-butyl-4-methyloctane
  2. 2,4-dimethylhexane
  3. 3-methyl-6-(propan-2-yl) nonane
  4. 2,4-dimethylheptane

Step by step solution

01

Step 1: Elucidation of organic compounds by IUPAC nomenclature

The longest carbon chain is determined, and the carbon atoms in it are counted to get the root word. The root word is used as a suffix.

  • Four carbon atoms-But
  • Five carbon atoms-Pent
  • Six carbons atoms- Hex
02

IUPAC rules for naming

The bonds are represented by suffixes.

  • -ane: single bond
  • -ene: double bond
  • -yne: triple bond

After this, the substituent is observed, and the prefix is determined by using the lowest possible numbers.Multiple substituents are named on the basis of preferences and alphabetical order.

03

IUPAC names of the given compounds

a. In the structure, the largest carbon chain is octane. Here, the substituents are methyl and tertiary butyl.

The position and the order of substituents give the name of the compound as 4-tert-butyl-4-methyloctane.

b. In the structure, the largest carbon chain is hexane. Here, the substituents are two methyl groups.

The position and the order of substituents give the name of the compound as 2,4-dimethylhexane.

c. In the structure, the largest carbon chain is nonane.Here, the substituents are methyl and propyl groups.

The position and the order of substituent give the name of the compound as3-methyl-6-(propan-2-yl)nonane.

d. In the structure, heptane is the longest chain.Here, the substituents are two methyl groups.

The position and the order of substituent give the name of the compound as 2,4-dimethylheptane.

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Most popular questions from this chapter

Question: Mineral oil, a mixture of high molecular weight alkanes, is sometimes used as a laxative. Why are individuals who use mineral oil for this purpose advised to avoid taking it at the same time they consume foods rich in fat-soluble vitamins such as vitamin A?

Question: The melting points and boiling points of two isomeric alkanes are as follows: CH3(CH2)6CH3, mp=-570C and bp=1260C;(CH3)3CC(CH3)3 , mp=1020C and bp=1060C.

a. Explain why one isomer has a lower melting point but higher boiling point.

b. Explain why there is a small difference in the boiling points of the two compounds but a huge difference in their melting points.

Question: Draw both conformations for 1-ethyl-1-methylcyclohexane and decide which conformation (if any) is more stable.

Question: Answer the following questions about compound A, which contains a -CH3group and OH group bonded to the carbon skeleton that consists of three six-membered rings in the conformation shown.

a. Are the -CH3and OH groups oriented cis or trans to each other?

b. Is a substituent on localid="1648626189057" Cathat is cis to the CH3 group located in the axial or equatorial position?

c. Is an equatorial Br at Cboriented cis or trans to the OH group?

d. Is the H atom on Cclocated cis or trans to the OH group?

e. Is a substituent on Cdthat is trans to the OH group located in the axial or equatorial position?

Question: Classify each pair of compounds as constitutional isomers, stereoisomers, identical molecules, or not isomers of each other.

a.

b.

c.

d.

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