Chapter 10: Q.15. (page 401)
Question: Draw the products formed when each alkene is treated with HCl.
Short Answer
Answer
Chapter 10: Q.15. (page 401)
Question: Draw the products formed when each alkene is treated with HCl.
Answer
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Get started for freeQuestion: Like other electrophiles, carbocations add to alkenes to form new carbocations, which can then undergo substitution or elimination reactions depending on the reaction conditions. With this in mind, consider the following reactions of nerol, a natural product isolated from lemon grass and other plant sources. Treatment of nerol with TsOH forms α-terpineol as the major product, whereas treatment of nerol with chlorosulfonic acid, HSO3Cl , forms a constitutional isomer, α-cyclogeraniol. Write stepwise mechanisms for both processes. Each mechanism involves the addition of an electrophile—a carbocation— to a double bond.
Question: Less stable alkenes can be isomerized to more stable alkenes by treatment with strong acid. For example, 2,3-dimethylbut-1-ene is converted to 2,3-dimethylbut-2-ene when treated with . Draw a stepwise mechanism for this isomerization process.
Question: What alkylborane is formed from hydroboration of each alkene?
Question: Devise a synthesis of each compound from the indicated starting material.
Question: Draw a stepwise mechanism for the conversion of hex-5-en-1-ol to the cyclic ether A.
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