Chapter 10: Q.32. (page 419)
Question: What alkylborane is formed from hydroboration of each alkene?
Short Answer
Answer
- (E)-3,5-dimethylhex-2-ene.
- 1-sec-butyl-2-methylcyclopent-1-ene
Chapter 10: Q.32. (page 419)
Question: What alkylborane is formed from hydroboration of each alkene?
Answer
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Get started for freeQuestion: What alkene can be used to prepare each alcohol as the exclusive product of a two-step hydroboration–oxidation sequence?
Question: a. Which diastereomer of oct-4-ene yields a mixture of two enantiomers, (4R,5R)- and (4S,5S)-4,5-dibromooctane on reaction with Br2 ?
b. Which diastereomer of oct-4-ene yields a single meso compound, (4R,5S)-4,5-dibromooctane?
Question: Alkene A can be isomerized to isocomene, a natural product isolated from goldenrod, by treatment with TsOH. Draw a stepwise mechanism for this conversion. (Hint: Look for a carbocation rearrangement.)
Question: Addition of HBr to which of the following alkenes will lead to a rearrangement?
Question: Draw a stepwise mechanism for the following reaction. Draw the transition state for each step.
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