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Chapter 25: 48 (page 1043)

What amide(s) can be used to prepare each amine by reduction?

(a)

(b)

(c)

Short Answer

Expert verified

(a)

(b)

(c)

Step by step solution

01

Reduction reaction

The reduction of amides into amines can be done in the presence of reducing agents. In this reaction, lithium aluminum hydride is used.

02

Explanation

(a)

The structure of the amide that is needed to form the amine by reduction is mentioned below.


Structure of amide in a

(b)

The structure of the amide that is needed to form the amine by reduction is mentioned below.

Structure of amide in b

(c)

The structure of the amide that is needed to form the amine by reduction is mentioned below.

Structure of amide in c

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Most popular questions from this chapter

Question: Devise a synthesis of each compound from aniline (C6H5NH2)

a.

b.

A chiral amine A having the R configuration undergoes Hofmann elimination to form an alkene B as the major product. B is oxidatively cleaved with ozone, followed by CH3SCH3 , to form CH2=O andCH3CH2CH2CHO .What are the structures of A and B?

Tertiary ( 3°) aromatic amines react with NaNO2 and HCl to afford products of electrophilic aromatic substitution. Draw a stepwise mechanism for this nitrosation reaction and explain why it occurs only on benzene rings with strong ortho, para activating groups.

Question: Label the stereogenic centers in each compound.

a.

b.

Question: Name each amine.

a.

b.

c.

d.

e.

f.
See all solutions

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