Chapter 25: 53 (page 1043)
Draw the products formed when each amine is treated with [1] (excess); [2] ; [3] . Indicate the major product when a mixture results.
a

b

c

d

Short Answer
a

b

c

d

Chapter 25: 53 (page 1043)
Draw the products formed when each amine is treated with [1] (excess); [2] ; [3] . Indicate the major product when a mixture results.
a

b

c

d

a

b

c

d

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Question: Label the stereogenic centers in each compound.
a.

b.

Draw the product Y of the following reaction sequence. Y was an intermediate in the remarkable synthesis of cyclooctatetraene by Wilstatter in 1911.

Question: Give a systematic or common name for each compound.
a.

b.

c.

d.

e.

f.

g.

h.

Explain why m-nitroaniline is a stronger base than p-nitroaniline
Treatment of compound D with followed by forms compound E. D shows a molecular ion in its mass spectrum at m/z= 71 and IR absorptions at and . E shows a molecular ion in its mass spectrum at m/z= 75 and IR absorptions at and . Propose structures for D and E from these data and the given 1H NMR spectra.


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