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Chapter 25: PROBLEM 25.29 (page 1029)

Question: Draw the product formed when each compound is treated with NaNO2 and HCl.

a.

b.

c.

d.


Short Answer

Expert verified

Answer

a.

b.

c.

d.

Step by step solution

01

Diazotization reaction

The diazotization reaction occurs between an amine and NaNO2 , HCl. The reagent gives the nitrous acid, which the amine substrate attacks to form products.

02

Reaction of primary, secondary amine

  • The primary amine on the reaction with NaNO2 and HCl gives a salt.
  • The secondary amine on the reaction with NaNO2 and HCl gives a nitrosoamine product.
03

Explanation

a. The given amine is a primary amine which gives the product as:

Product formation from a.

b. The given amine is a secondary amine which gives the product as:

Product formation from b.

c. The given amine is a secondary amine which gives the product as:

Product formation from c.

d. The given amine is a primary amine which gives the product as:

Product formation from d.

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Most popular questions from this chapter

Question: Draw the product Y of the following reaction sequence. Y was an intermediate in the remarkable synthesis of cyclooctatetraene by Wilstatter in 1911.

Question: Which N atom in each compound is more basic? What product is formed when each compound is treated with HCl?

a.

b.

Why is pyrrole more acidic than pyrrolidine?

Question:The pKa of the conjugate acid of guanidine is 13.6, making it one of the strongest neutral organic bases. Offer an explanation.

Question: Rank the following compounds in order of increasing basicity
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