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Chapter 25: PROBLEM 25.32 (page 1035)

Question: Draw the product formed when C6H5N2+Cl– reacts with each compound.

a.

b.

c.

Short Answer

Expert verified

Answer

(a)

(b)

(c)

Step by step solution

01

Formation of azo compounds

Diazonium compound is reacted with another aromatic compound to give an azo compound, a compound containing a nitrogen-nitrogen double bond

This is an electrophilic aromatic substitution

02

Curved arrow mechanism

a. The diazonium salt acts as an electrophile and the activated aniline acts as a nucleophile.


Reaction with aniline

b. The diazonium salt acts as an electrophile and the activated phenol acts as a nucleophile

Reaction with phenol

c. The diazonium salt acts as an electrophile and 1,4-dihydroxybenzene acts as a nucleophile

Reaction with 1,4-dihydroxybenzene

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