Chapter 29: Q2. (page 1156)
What form exists at the isoelectric point of each of the following amino acids: (a) valine; (b)leucine; (c)proline; (d) glutamic acid.
Short Answer
(a)

Chapter 29: Q2. (page 1156)
What form exists at the isoelectric point of each of the following amino acids: (a) valine; (b)leucine; (c)proline; (d) glutamic acid.
(a)
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Get started for freeDraw the products of each reaction.
(a)
(b)
(c)
(d)
Draw the structure of leu-enkephalin, a pentapeptide that acts as an analgesic and opiate, and has the following sequence: Tyr–Gly–Gly–Phe–Leu. (The structure of a related peptide, met-enkephalin,
appeared in Section 22.6B.)
Devise a synthesis of each amino acid from acetaldehyde:
(a) Glycine;
(b) Alanine.
Draw the organic products formed in each reaction.
a. Draw the structure of the tripeptide A-A-A, and label the two ionizable functional groups.
b. What is the predominant form of A-A-A at pH=1?
c. The values for the two ionizable functional groups (3.39 and 8.03) differ considerably from the values of alanine (2.35 and 9.87;see table 29.1). Account for the observed differences.
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