Chapter 29: Q39. (page 1192)
Draw the organic products formed in each reaction.
Short Answer
c.
Chapter 29: Q39. (page 1192)
Draw the organic products formed in each reaction.
c.
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Get started for freeDraw all the steps in the synthesis of each peptide from individual amino acids:
Gly-Ala;
Devise a synthesis of the following dipeptide from amino acid starting materials.
What is the predominant form of each of the following amino acids at pH=1? What is the overall charge on the amino acid at this pH?(a)threonine ; (b)methionine; (c)aspartic acid; (d)arginine
Besides the Boc and Fmoc protecting groups used in peptide synthesis, amines can also be protected by reaction with benzyl chloroformate (). Draw the structure of the product formed by reaction of alanine with benzyl chloroformate
a.(S)-Penicillamine, an amino acid that does not occur in proteins, is used as a copper chelating agent to treat Wilson’s disease, an inherited defect in copper metabolism.
(R)-Penicillamine is toxic, sometimes causing blindness. Draw the structures of (R) and (S)-penicillamine.
b. What disulfide is formed from oxidation of L-penicillamine?
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