Chapter 29: Q51P (page 1194)
Draw the structure for each peptide:
(a) Phe–Ala;
(b) Gly–Gln;
(c) Lys–Gly;
(d) R-H
Short Answer
a.
b.
C.
d.
Chapter 29: Q51P (page 1194)
Draw the structure for each peptide:
(a) Phe–Ala;
(b) Gly–Gln;
(c) Lys–Gly;
(d) R-H
a.
b.
C.
d.
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Get started for freeGlutamic acid is synthesized by the following reaction sequence. Draw a stepwise mechanism for Steps [1]–[3].
Devise a synthesis of each amino acid from acetaldehyde :
(a) Glycine;
(b) Alanine.
Question: Propose a structure for a compound of molecular formula \({{\bf{C}}_{\bf{7}}}{{\bf{H}}_{{\bf{14}}}}{{\bf{O}}_{\bf{2}}}\) with an IR absorption at \({\bf{1740}}\;{\bf{c}}{{\bf{m}}^{{\bf{ - 1}}}}\) and the following \({}^{\bf{1}}{\bf{H}}\) NMR data:
\(\begin{array}{*{20}{c}}{{\bf{Absorption}}}&{{\bf{ppm}}}&{{\bf{Relative}}\;{\bf{area}}}\\\hline{{\bf{singlet}}}&{{\bf{1}}{\bf{.2}}}&{\bf{9}}\\{{\bf{triplet}}}&{{\bf{1}}{\bf{.3}}}&{\bf{3}}\\{{\bf{quartet}}}&{{\bf{4}}{\bf{.1}}}&{\bf{2}}\end{array}\)
Draw all the steps in the synthesis of each peptide from individual amino acids:
Gly-Ala;
How many different tripeptides can be formed from three different amino acids?
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