Chapter 28: Problem 28.44 (page 1148)
Draw the anomer of a monosaccharide epimeric with D-glucose at C2 using a Haworth projection.
Short Answer
Answer
Chapter 28: Problem 28.44 (page 1148)
Draw the anomer of a monosaccharide epimeric with D-glucose at C2 using a Haworth projection.
Answer
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Get started for freeQuestion: Assign R,S designations to each stereogenic center in glucose.
Question: Referring to Figure 28.5, which d-ketohexoses have the S configuration at C3?
Fig. 28.5
Question: Label each Haworth projection as an α or β anomer and convert the Haworth projection to a six-membered ring with wedges and dashed wedges.
a.
b.
Draw a Haworth projection for each compound using the structures in Figures 28.4 and 28.5.
The most stable conformation of the pyranose ring of most D-aldohexoses places the largest group, , in the equatorial position. An exception to this is the aldohexose D-idose. Draw the two possible chair conformations of either the or anomers of D-idose. Explain why the more stable conformation has the group in the axial position.
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