Chapter 26: Q 15. (page 1066)
Draw the product formed from ring-closing metathesis of each compound.
a.
b.
Short Answer
Answer
b.
Chapter 26: Q 15. (page 1066)
Draw the product formed from ring-closing metathesis of each compound.
a.
b.
Answer
b.
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Get started for freeWhat starting material is needed to synthesize each compound by a ring-closing metathesis reaction?
a.
b.
c.
Although diazomethane ( ) is often not a useful reagent for preparing cyclopropanes,other diazo compounds give good yields of more complex cyclopropanes. Draw a stepwisemechanism for the conversion of diazo compound A to B, an intermediate in the synthesis ofsirenin, the sperm attractant produced by the female gametes of the water mold Allomyces.
Devise a synthesis of each compound using a Heck reaction as one step. You may use benzene, , organic alcohols having two carbons or fewer and any required inorganic reagents.
a.
b.
Dimethyl cyclopropanes can be prepared by the reaction of an α, β-unsaturated carbonyl compound X with two equivalents of a Wittig reagent Y. Draw a stepwise mechanism for this reaction.
Identify X, an intermediate that was converted to eletriptan (trade name Relpax), a drug used to treat migraines.
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