Chapter 26: Q 21. (page 1069)
What organic halide is needed to convert lithium divinylcuprate to each compound?
a.
b.
c.
Short Answer
Answer
a.
b.
c.
Chapter 26: Q 21. (page 1069)
What organic halide is needed to convert lithium divinylcuprate to each compound?
a.
b.
c.
Answer
a.
b.
c.
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Get started for freeAlthough diazomethane ( ) is often not a useful reagent for preparing cyclopropanes,other diazo compounds give good yields of more complex cyclopropanes. Draw a stepwisemechanism for the conversion of diazo compound A to B, an intermediate in the synthesis ofsirenin, the sperm attractant produced by the female gametes of the water mold Allomyces.
What starting material is needed to synthesize each compound by a ring-closing metathesis reaction?
a.
b.
c.
What steps are needed to convert but-1-ene to octane role="math" localid="1649049664153" using a coupling reaction with an organocuprate reagent? All carbon atoms in octane must come from but-1-ene.
Devise a synthesis of each of the following compounds. Besides inorganic reagents, you may use hydrocarbons and halides having C’s, and as starting materials. Each synthesis must use at least one of the carbon–carbon bond-forming reactions in this chapter.
b.
c.
d.
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