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Chapter 26: Q 34. (page 1071)

Draw the products formed in each reaction.

Short Answer

Expert verified

Answer

a.

Product of a

b.

Product of b

c.

Product of c

d.

Product of d

e.

Product of e

f.

Product of f

g.

Product of g

h.

Product of h

Step by step solution

01

Suzuki reaction

This is a cross-coupling reaction in which the boronic acid R-BY2and the organohalide compounds react to form polyolefins, styrenes, and substituted biphenyls.

02

Heck reaction  

The unsaturated organohalide compound reacts with an alkene in the presence of a base and the catalyst palladium to form substituted alkenes.

03

Products of the given reaction

a. The products of the given reaction are given below.

Products of a

b. The products of the given reaction are given below.


Products of b

c. The products of the given reaction are given below.

Products of c

d. The products of the given reaction are given below.

Products of d

e. The products of the given reaction are given below.

Products of e

f. The products of the given reaction are given below.

Products of f

g. The products of the given reaction are given below.

Products of g

h. The products of the given reaction are given below.

Products of h

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Most popular questions from this chapter

Devise a synthesis of each compound using a Heck reaction as one step. You may use benzene, CH2=CHCO2Et, organic alcohols having two carbons or fewer and any required inorganic reagents.

a.

b.

Devise a synthesis of each compound from benzene. You may also use any organic compounds having four carbons or fewer, and any required inorganic reagents.

a.

b.

What starting material is needed to synthesize each compound by a ring-closing metathesis reaction?

a.

b.

c.

Metathesis reactions can be carried out with two different alkene substrates in one reaction mixture. Depending on the substitution pattern around the C=C, the reaction may lead to one major product or a mixture of many products. For each pair of alkene substrates, draw all metathesis products formed. (Disregard any starting materials that may also be present at equilibrium.) With reference to the three examples, discuss when alkene metathesis with two different alkenes is a synthetically useful reaction.

Treatment of cyclohexene with C6H5CHI2and Zn(Cu) forms two stereoisomers of molecular formula C13H16. Draw their structures and explain why two compounds are formed.
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