Chapter 26: Q 4. (page 1054)
Draw the product of each reaction.
Short Answer
Answer
a.
b.
c.
d.
Chapter 26: Q 4. (page 1054)
Draw the product of each reaction.
Answer
a.
b.
c.
d.
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Get started for freeSulfur ylides, like the phosphorus ylides of Chapter 21, are useful intermediates in organic synthesis. Methyl trans-chrysanthemate, an intermediate in the synthesis of the insecticide pyrethrin I (Section 26.4), can be prepared from diene A and a sulfur ylide. Draw a stepwise mechanism for this reaction.
Devise a synthesis of each compound using a Heck reaction as one step. You may use benzene, , organic alcohols having two carbons or fewer and any required inorganic reagents.
a.
b.
Identify reagents A and B in the following reaction scheme. This synthetic sequence was used to prepare the C18 juvenile hormone (Figure 20.6).
What product is formed when each alkene is treated with and Zn(Cu)?
a.
b.
c.
What stereoisomers are formed when trans-hex-3-ene is treated with and Zn(Cu)?
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