Chapter 26: Q19P (page 1049)
What product is formed by ring-closing metathesis of each compound?
a.

b.

Short Answer
a.

b.

Chapter 26: Q19P (page 1049)
What product is formed by ring-closing metathesis of each compound?
a.

b.

a.

b.

All the tools & learning materials you need for study success - in one app.
Get started for free
Draw the structure of the two products of molecular formula formed when M is treated with Grubbs catalyst under high-dilution conditions.

In addition to organic halides, alkyl tosylates (R'OTs, Section 9.13) also react with organocuprates ( ) to form coupling products R-R'. When 2° alkyl tosylates are used as starting materials ( ), inversion of the configuration at a stereogenic center results. Keeping this in mind, draw the product formed when each compound is treated with .
a.

b.

What compound is needed to convert styrene to each product using a Heck reaction?
a.

b.

c.

Sulfur ylides, like the phosphorus ylides of Chapter 21, are useful intermediates in organic synthesis. Methyl trans-chrysanthemate, an intermediate in the synthesis of the insecticide pyrethrin I (Section 26.4), can be prepared from diene A and a sulfur ylide. Draw a stepwise mechanism for this reaction.

Synthesize each compound from the given starting materials.

What do you think about this solution?
We value your feedback to improve our textbook solutions.