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Chapter 24: Q.19. (page 962)

Question: Draw the products of each reaction.

Short Answer

Expert verified

Answer

a.

b.

Step by step solution

01

Crossed Claisen reaction

The reaction between an ester and diethyl ester or chloroformate also falls in the category of Crossed Claisen reaction.

02

Crossed Claisen reaction mechanism

The reaction between ketone and chloroformate is represented below:

Claisen reaction

03

Products of the given reaction

a. The reaction of the ester with given reagents is shown below.

Reaction a.

b. The reaction of the ester with given reagents is shown below.

Reaction b.

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Most popular questions from this chapter

Question: Draw a stepwise mechanism for the following Robinson annulation. This reaction was a key step in a synthesis of the steroid cortisone by R. B. Woodward and co-workers at Harvard University in 1951.

Question: What steps are needed to convert A to B?

Question:Even though B contains three ester groups, a single Dieckmann product results when B is treated with NaOCH3in CH3OH, followed by H3O+. Draw the structure and explain why it is the only product formed.

Question: Devise a synthesis of each compound from CH3CH2CH2CO2Et, benzene, and alcohols having ≤ 2 C's. You may also use any required organic or inorganic reagents.

Question: Following the two-step reaction sequence depicted in Figure 24.5, write out the steps needed to convert A to B.
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