Chapter 22: Q31. (page 908)
Question: Draw the products of each reaction.
a.
b.
c.
Short Answer
Answer
a.
b.
c.
Chapter 22: Q31. (page 908)
Question: Draw the products of each reaction.
a.
b.
c.
Answer
a.
b.
c.
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Get started for freeQuestion: Draw a tautomer of each compound.
a.
b.
c.
Question: How do the following experimental results support the resonance description of the relative stability of acid chlorides compared to amides? The C-Cl bond lengths in and CH3COCl are identical (178 pm), but the C-N bond in is shorter than the C-N bond in (135 pm versus 147 pm).
Draw the product formed when pentanal (CH3CH2CH2CH2CHO ) is treated with each reagent. With some reagents, no reaction occurs.
a. NaBH4 , CH3OH
b. {1} LiAlH4 ; {2} H2O
c. H2,Pd-C
d. PCC
e. Na2Cr2O7, H2SO4, H2O
f. Ag2O, NH4OH
g. {1}CH3MgBr ; {2} H2O
h. {1} C6H5Li ; {2} H2O
i. {1} (CH3)2CuLi ; {2} H2O
l. The product in (a) , then TBDMS-Cl , imidazole
Question: Draw the products of each reaction
a.
b.
What carbonyl compound and CBS reagent are needed to prepare X, an
intermediate in the synthesis of ezetimibe (trade name Zetia), a drug that lowers cholesterol levels by inhibiting its absorption in the intestines.
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