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Chapter 22: Q50. (page 916)

Question: Identify compounds A–M in the following reaction sequence.

Short Answer

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Answer

Step by step solution

01

Step-by-Step Solution Step 1: Chemical properties of carboxylic acid

Carboxylic acid has a carbonyl group. Therefore, it undergoes nucleophilic addition as well as nucleophilic substitution reactions.

The conversion of carboxylic acid to acid chloride is one of the chemical properties of carboxylic acid in the presence of thionyl chloride.

02

Reduction of nitrile

Reduction of nitriles occurs in the presence of lithium aluminium hydride, which produces hydride ion to nitrile and reduces the nitrile into primary amine.

03

Explanation

The conversion of the given reactants into the products is shown as:

Conversions

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Most popular questions from this chapter

What amide(s) will form each of the following amines on treatment with LiAlH₄?

Question: Rank the compounds in each group in order of increasing reactivity in nucleophilic acyl substitution.

$a . C_{6} H_{5} {CO}_{2} {CH}_{3,} C_{6} H_{5} COCl, C_{6} H_{5} {CONH}_{2} b . {CH}_{3} {CH}_{2} {CO}_{2} H, {({CH}_{3} {CH}_{2} CO)}_{2} O, {CH}_{3} {CH}_{2} {CONHCH}_{3}$

Which carbon is most electrophilic in Compound Y? Explain your choice.

Question: Explain why the boiling point of ${CH}_{3} {CONH}_{2} (221 ° C)$ is significantly higher than the boiling point of ${CH}_{3} {CO}_{2} H$ .

What Grignard reagent and carbonyl compound are needed to prepare each alcohol? As shown in part (d), 3^o alcohols with three different R groups on the carbon bonded to the OH group can be prepared by three different Grignard reactions.

See all solutions

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