Chapter 20: Q35 (page 805)
Synthesize each compound from cyclohexanol, ethanol, and any other needed reagents.
a.
b.
c.
d.
e.
Short Answer
The given products can be synthesized through the following method:
a.
b.
c.
d.
e.
Chapter 20: Q35 (page 805)
Synthesize each compound from cyclohexanol, ethanol, and any other needed reagents.
a.
b.
c.
d.
e.
The given products can be synthesized through the following method:
a.
b.
c.
d.
e.
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Get started for freeWhat epoxide and organometallic reagents are needed to synthesize each alcohol?
Explain why the carbon of an ,-unsaturated carbonyl compound absorbs farther downfield in the NMR spectrum than the a carbon, even though the carbon is closer to the electron-withdrawing carbonyl group. For example, the carbon of mesityl oxide absorbs at 150.5 ppm, while the carbon absorbs at 122.5 ppm.
Reaction of butane nitrile with methyl magnesium bromide , followed by treatment with aqueous acid, forms compound G. G has a molecular ion in its mass spectrum at m/z = 86 and a base peak at m/z = 43. G exhibits a strong absorption in its IR spectrum at 1721 and has the NMR spectrum given below. What is the structure of G? We will learn about the details of this reaction in Chapter 22.
An unknown compound A (molecular formula ) was treated with to form compound B (molecular formula ). Compound A has a strong absorption in its IR spectrum at 1716 . Compound B has a strong absorption in its IR spectrum at 3600–3200 . The NMR spectra of A and B are given. What are the structures of A and B?
Draw all stereoisomers formed in each reaction.
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