Chapter 31: Q11. (page 1231)
Question: Locate the isoprene units in biformene, a component of amber, and classify biformene as a monoterpene, sesquiterpene etc.

Short Answer
Answer

Biformene is a sesquiterpene.
Chapter 31: Q11. (page 1231)
Question: Locate the isoprene units in biformene, a component of amber, and classify biformene as a monoterpene, sesquiterpene etc.

Answer

Biformene is a sesquiterpene.
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Treatment of cholesterol with mCPBA results in formation of a single epoxide A, with the stereochemistry drawn. Why isn’t the isomeric epoxide B formed to any extent?

Question: An isoprene unit can be thought of as having a head and a tail. The “head” of the isoprene unit is located at the end of the chain nearest the branch point, and the “tail” is located at the end of the carbon chain farthest from the branch point. Most isoprene units are connected together in a “head-to-tail” fashion, as illustrated. For both lycopene (Problem 31.26), and squalene (Figure 31.9), decide which isoprene units are connected in a head-to-tail fashion and which are not.

Consider separate 1.0-L samples of O2(g) and He(g), both at 25oC and the same pressure. Compare the change in momentum per impact and the number of impacts per second in the two samples.
Convert the ball-and-stick model of androsterone to (a) a skeletal structure using wedges and dashed wedges around all stereogenic centers; and (b) a three-dimensional representation using chair cyclohexane rings.

Question: Locate the isoprene units in each compound.
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