Chapter 14: Q.21558-14-25P. (page 555)
Propose a structure for a compound of molecular formula C3H8O with an IR absorption at 3600 to 3200 cm-1 and the following NMR spectrum:
Chapter 14: Q.21558-14-25P. (page 555)
Propose a structure for a compound of molecular formula C3H8O with an IR absorption at 3600 to 3200 cm-1 and the following NMR spectrum:
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Get started for freeWhich of the highlighted carbon atoms in each molecule absorbs farther downfield?
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h.
Question: Treatment of 2-methylpropanenitrile [(CH3)2CHCN] with CH3CH2CH2MgBr, followed by aqueous acid, affords compound V, which has molecular formula C7H14O. V has a strong absorption in its IR spectrum at 1713 cm-1, and gives the following 1 H NMR data: 0.91 (triplet, 3 H), 1.09 (doublet, 6 H), 1.6 (multiplet, 2 H), 2.43 (triplet, 2 H), and 2.60 (septet, 1 H) ppm. What is the structure of V? We will learn about this reaction in Chapter 22.
Question: Identify the structures of isomers H and I (molecular form C8H11N)
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b.
Question: The 1 H NMR spectrum of N,N-dimethylformamide shows three singlets at 2.9, 3.0, and 8.0 ppm. Explain why the two groups are not equivalent to each other, thus giving rise to two NMR signals.
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