Chapter 12: PROBLEM 12.20 (page 475)
Question: What alkene yields each set of oxidative cleavage products?
a.
b.
Short Answer
Answer
a.
b.
c.
Chapter 12: PROBLEM 12.20 (page 475)
Question: What alkene yields each set of oxidative cleavage products?
a.
b.
Answer
a.
b.
c.
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Get started for freeQuestion: Identify compounds A, B, and C.
a. Compound A has molecular formula and reacts with two equivalents of . A gives as the only product of oxidative cleavage with followed by.
b. Compound B has molecular formula and gives when treated with excess in the presence of Pd. B reacts with and to form compound C (molecular formula ).
Question:Devise a synthesis of (3R,4S)-3,4-dichlorohexane from acetylene and any needed organic compounds or inorganic reagents.
Question:What epoxide is formed when each alkene is treated with mCPBA?
a.
b.
c.
Question: Devise a synthesis of each compound from as the only organic starting material; that is, every carbon in the product must come from a molecule of ethanol. You may use any other needed inorganic reagents.
Draw the organic products formed when cyclopentene is treated with each reagent. With some reagents, no reaction occurs.
a. H2+Pd-C
b. H2+ Lindlar catalyst
c. Na ,NH3
d. CH3CO3H
e. [1]. CH3CO3H [2] H2O ,OH-
f. [1] OSO4+NMO [2] NaHSO3, H2O
g.KMnO4 ,H2O ,OH-
h. [1] LiAlH4 [2] H2O
i. [1] O3 .[2] H3CSCH3
j. (CH3)3COOH ,Ti [OCH(CH3)3]4 (-) DET
k. mCPBA
l.Product in (k); Then[1] LiAlH4 [2] H2O
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