Chapter 15: Q14. (page 570)
Question: Draw the monochlorination products formed when each compound is heated with Cl2. Include the stereochemistry at any stereogenic center.
a.

b.

c.

d.

Short Answer
Answer
a.

b.

c.

d.

Chapter 15: Q14. (page 570)
Question: Draw the monochlorination products formed when each compound is heated with Cl2. Include the stereochemistry at any stereogenic center.
a.

b.

c.

d.

Answer
a.

b.

c.

d.

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Question:Draw the products formed in each reaction and include the stereochemistry around any stereogenic centers.
a.

b.

c.

d.

Question: Draw the steps of the mechanism that converts vinyl chloride (CH2CHCl) into poly(vinyl chloride).
Question: Five isomeric alkanes (A–E) having the molecular formula C6H14 are each treated with Cl2 + hv to give alkyl halides having molecular formula C6H13Cl . A yields five constitutional isomers. B yields four constitutional isomers. C yields two constitutional isomers. D yields three constitutional isomers, two of which possess stereo-genic centres. E yields three constitutional isomers, only one of which possesses a stereo-genic centre. Identify the structures of A–E.
Question: Devise a synthesis of 1-methylcyclohexene oxide from methylcyclohexane. You may use any other required organic or inorganic reagents.
Question: Which C-H bond is most readily cleaved in linoleic acid? Draw all possible resonance structures for the resulting radical. Draw all the hydroperoxides formed by the reaction of this resonance stabilized radical with O2.

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