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Chapter 15: Q14. (page 570)

Question: Draw the monochlorination products formed when each compound is heated with Cl2. Include the stereochemistry at any stereogenic center.

a.

b.

c.

d.

Short Answer

Expert verified

Answer

a.

b.

c.

d.

Step by step solution

01

Monochlorination of alkane

It involves the substitution of one hydrogen atom by a chlorine atom in the presence of heat or sunlight.

02

Formation of products in a and b

a.

The reaction is shown below.

Product formation in a

b.

The reaction is shown below.

Product formation in b

c.

The reaction is shown below.

Product formation in c

d.

The reaction is shown below.

Product formation in d

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Most popular questions from this chapter

Question: When 3,3-dimethylbut-1-ene is treated with HBr alone, the major product is 2-bromo-2,3- dimethylbutane. When the same alkene is treated with HBr and peroxide, the sole product is 1-bromo-3,3-dimethylbutane. Explain these results by referring to the mechanisms.

Question: Nitric oxide, NO•, is another radical also thought to cause ozone destruction by a similar mechanism. One source of NO• in the stratosphere is supersonic aircraft whose jet engines convert small amounts of N2 and O2 to NO•. Write the propagation steps for the reaction of O3 with NO•

Question: Rank the following radicals in order of increasing stability.

Question: Draw the products formed when each alkene is treated with NBS + hv .

a.

b.

c.

Question: Draw a stepwise mechanism for the following reaction.
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