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Chapter 15: Q16. (page 570)

Question: Draw a second resonance structure for each radical. Then draw the hybrid.

a.

b.

c.

d.

Short Answer

Expert verified

Answer

a.

b.

c.

d.

Step by step solution

01

Radical halogenation

It is a type of halogenation that gives an alkyl halide using a radical.

02

Formation of products

a.

The resonance and hybrid of the given radical are shown below.

Resonance and hybrid in a

b.

The resonance and hybrid of the given radical are shown below.

Resonance and hybrid in b

c.

The resonance and hybrid of the given radical are shown below.

Resonance and hybrid in c

d.

The resonance and hybrid of the given radical are shown below.

Resonance and hybrid in d

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Most popular questions from this chapter

Consider the following Bromination:

(a) Calculate ΔH° for this reaction by using the bond dissociation energies in Table 6.2.

(b) Draw out a stepwise mechanism for the reaction, including the initiation, propagation, and termination steps.

(c) Calculate ΔH° for each propagation step.

(d) Draw an energy diagram for the propagation steps.

(e) Draw the structure of the transition state of each propagation step

Question: Draw the products formed when a chlorine atom reacts with each species.

a.

b.

c.

d. O2

Question:A and B, isomers of molecular formula C3H5Cl3 , are formed by the radical chlorination of a dihalide C of molecular formula C3H6Cl2 .

(a) Identify the structures of A and B from the following NMR data:

Compound A: singlet at 2.23 and singlet at 4.04 ppmCompound B: doublet at 1.69, multiplet at 4.34, and a doublet at 5.85 ppm

(b) What is the structure of C?

Question: Which C-H bond is most readily cleaved in linoleic acid? Draw all possible resonance structures for the resulting radical. Draw all the hydroperoxides formed by the reaction of this resonance stabilized radical with O2.

Questions: Why is a benzylic C-H bond unusually weak?
See all solutions

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