Chapter 15: Q29. (page 570)
Question: Draw all resonance structures of the radical that results from abstraction of a hydrogen atom from the antioxidant BHA (butylated hydroxy anisole).
Short Answer
Answer
Chapter 15: Q29. (page 570)
Question: Draw all resonance structures of the radical that results from abstraction of a hydrogen atom from the antioxidant BHA (butylated hydroxy anisole).
Answer
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Get started for freeQuestion: In the presence of a radical initiator (Z* ), tributyltin hydride ( R3SnH,R=CH3CH2CH2CH2 ) reduces alkyl halides to alkanes: R'X+R3SnHR'H+R3SnX. The mechanism consists of a radical chain process with an intermediate tin radical:
This reaction has been employed in many radical cyclization reactions. Draw a stepwise mechanism for the following reaction.
Question:What reagents are needed to convert cyclopentene into
(a)bromocyclopentane;
(b) trans-1,2-dibromocyclopentane;
(c) 3-bromocyclopentene?
Question: a. What product(s) (excluding stereoisomers) are formed when Y is heated with Cl2 ?
b. What product(s) (excluding stereoisomers) are formed when Y is heated with Br2?
c. What steps are needed to convert Y to the alkene Z?
Question: Five isomeric alkanes (A–E) having the molecular formula C6H14 are each treated with Cl2 + hv to give alkyl halides having molecular formula C6H13Cl . A yields five constitutional isomers. B yields four constitutional isomers. C yields two constitutional isomers. D yields three constitutional isomers, two of which possess stereo-genic centres. E yields three constitutional isomers, only one of which possesses a stereo-genic centre. Identify the structures of A–E.
Questions: Rank the indicated hydrogen atoms in order of increasing ease of abstraction in a radical halogenation reaction.
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