Chapter 5: Q.8 (page 183)
Locate the stereogenic center in each compound and draw both enantiomers.
a.
b.
c.
Short Answer
The stereogenic centers in the given compounds and their enantiomers are represented below.
a.
b.
c.
Chapter 5: Q.8 (page 183)
Locate the stereogenic center in each compound and draw both enantiomers.
a.
b.
c.
The stereogenic centers in the given compounds and their enantiomers are represented below.
a.
b.
c.
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Get started for freeLocate the stereogenic centers in each molecule. Compounds may have one or more stereogenic centers.
b.
c.
d.
e.
f.
Cellulose is water insoluble, despite its many OH groups. Considering its three-dimensional structure, why do you think this is so?
a. Locate all the tetrahedral stereogenic centers in discodermolide, a tumor inhibitor isolated from the Caribbean marine sponge Discodermiadissoluta.
b. Certain carbon–carbon double bonds can also be stereogenic centers. With reference to the definition in Section 5.3, explain how this can occur, and then locate the three additional stereogenic centers in discodermolide.
c. Considering all stereogenic centers, what is the maximum number of stereoisomers possible for discodermolide?
What is the ee for each of the following mixtures of enantiomers A and B?
a. 95% A and 5% B
b. 85% A and 15% B
Artemisinin and mefloquine are widely used antimalarial drugs. A ball-and-stick model of artemisinin appears on the cover of this text.
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