For a reaction with ΔH°=40kJ/mol, decide which of the following statements is (are) true. Correct any false statement to make it true. (a) ΔG°The reaction is exothermic; (b) for the reaction is positive; (c) Keq is greater than 1; (d) the bonds in the starting materials are stronger than the bonds in the product; and (e) the product is favored at equilibrium.

Short Answer

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Answer

  1. False; The reaction is endothermic.
  2. True.
  3. False; Keqis less than 1.
  4. True.
  5. False; The reactant is favored at equilibrium.

Step by step solution

01

Step-by-Step SolutionStep 1: Change in enthalpy (ΔH°) and change in free (ΔG°) energy  

A negative value of ΔH°for a reaction indicates that the products are favored while a positive value indicates that reactants (i.e., the starting materials) are favored.

02

Change in enthalpy (ΔH°) and change in free energy (ΔG°) 

ΔH°is directly related to ΔG°and hence, the negative value of ΔG° also indicates that the products are favored.

03

Assigning true or false

(a) The reaction is exothermic

A positive value of ΔH°corresponds to an endothermic reaction and hence the given statement is false.

The correct statement should be - The reaction is endothermic.

(b) ΔG° for the reaction is positive

True, sinceΔH°is directly related toΔG°, a positive value ofΔH°corresponds to a positive value ofΔG°.

(c) Keqis greater than 1

False, as the positive value ofΔH°indicates that the reaction favors the reactants (i.e., the reaction proceeds backward).

The value of Keq for a backward reaction is always less than 1.

(d) The bonds in the starting materials are stronger than the bonds in the product.

True, Positive value of ΔH° indicates that the reactants or the starting materials are stronger than the bonds in the product.

(e) The product is favored at equilibrium.

False, the reactants are favored at equilibrium as ΔH°is positive.

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