Compound A can be converted to either B or C. The energy diagrams for both processes are drawn on the graph below.

  1. Label each reaction as endothermic or exothermic.
  2. Which reaction is faster?
  3. Which reaction generates the product lower in energy?
  4. Which points on the graphs correspond to transition states?
  5. Label the energy of activation for each reaction.
  6. Label the H° for each reaction.

Short Answer

Expert verified

Answer

  1. The reaction A to B is endothermic and reaction A to C is exothermic.
  2. The reaction that involves a lower activation energy barrier will be faster and hence in the given case, the reaction A to C is faster.
  3. Reaction A to C generates a product lower in energy.
  4. The points which have high energy (i.e., the points D and E) corresponds to the transition states.
  5. Labeled in the energy diagram
  6. Labeled in the energy diagram

Step by step solution

01

Step-by-Step SolutionStep 1: Exothermic and Endothermic reactions

The reactions that liberate energy/heat are termed exothermic and the ones that absorb heat are termed endothermic reactions.

  • The reactions that have a positive H°(i.e., the reactions in which the energy of products is higher than the energy of the reactants) are endothermic.
  • The reactions that have a negative H°(i.e., the reactions in which the energy of products is lower than that of the reactants) are exothermic.
02

Transition state and activation energy

In an energy profile diagram, the peak (high energy point) that lies between the reactants and the products is referred to as the transition state.

The energy barrier between the reactant and product species is referred to as the activation energy of the reaction.

03

Energy diagrams

Energy diagram of the given reactions

The reaction A to B is endothermic and reaction A to C is exothermic.

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Consider the following energy diagram for the conversion of AG.

a. Which points on the graph correspond to transition states?

b. Which points on the graph correspond to reactive intermediates?

c. How many steps are present in the reaction mechanism?

d. Label each step of the mechanism as endothermic or exothermic.

e. Label the overall reaction as endothermic or exothermic.

The conversion of (CH3)3Clto (CH3)2C=CH2can occur by either a one-step or a two-step mechanism, as shown in Equations [1] and [2].

a. What rate equation would be observed for the mechanism in Equation [1]?

b. What rate equation would be observed for the mechanism in Equation [2]?

c. What is the order of each rate equation (i.e., first, second, and so forth)?

d. How can these rate equations be used to show which mechanism is the right one for this reaction?

e. Assume Equation [1] represents an endothermic reaction and draw an energy diagram for the reaction. Label the axes, reactants, products, Ea, and H°. Draw the structure for the transition state.

f. Assume Equation [2] represents an endothermic reaction and that the product of the rate-determining step is higher in energy than the reactants or products. Draw an energy diagram for this two-step reaction. Label the axes, reactants and products for each step, and the Eaand H°for each step. Label H°overall. Draw the structure for both transition states.

Draw the products of each reaction by following the curved arrows.

a.

b.

Indicate which factors affect the rate of a reaction.

  1. G°
  2. H°
  3. Ea
  4. Temperature
  5. concentration
  6. width="28">Keq
  7. k
  8. Catalysts

For a reaction with Keq=0.8and Ea=80kJ/mol, decide which of the following statements is (are) true. Correct any false statement to make it true. Ignore entropy considerations. (a) The reaction is faster than a reaction with Keq=8and Ea=80kJ/mol. (b) The reaction is faster than a reaction with Keq=0.8and Ea=40kJ/mol. (c) G° for the reaction is a positive value. (d) The starting materials are lower in energy than the products of the reaction. (e) The reaction is exothermic.

See all solutions

Recommended explanations on Chemistry Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free