Using the symbols \(\delta\) - and \(\delta+\), indicate the direction of polarity, if any, in each covalent bond. (a) \(\mathrm{C}-\mathrm{Cl}\) (b) \(\mathrm{S}-\mathrm{H}\) (c) \(\mathrm{C}-\mathrm{S}\) (d) \(\mathrm{P}-\mathrm{H}\)

Short Answer

Expert verified
Question: Determine the direction of polarity in each bond using the symbols \(\delta-\) and \(\delta+\): (a) C-Cl (b) S-H (c) C-S (d) P-H Answer: (a) C\(\delta^+\) - Cl\(\delta^-\) (b) S\(\delta^-\) - H\(\delta^+\) (c) C - S (no polarity) (d) P - H (no polarity)

Step by step solution

01

Determine the electronegativity values of the bonded atoms

You can find the electronegativity values of the elements in the periodic table or any chemistry reference material. Here are the approximate electronegativity values for the relevant elements: - Carbon (C): 2.5 - Chlorine (Cl): 3.0 - Sulfur (S): 2.5 - Hydrogen (H): 2.1 - Phosphorus (P): 2.1
02

Compare the electronegativity values for each bond

Determine which atom in each bond has a higher electronegativity value. The atom with a higher value will have a partial negative charge (\(\delta-\)), while the atom with a lower value will have a partial positive charge (\(\delta+\)). (a) \(\mathrm{C}-\mathrm{Cl}\): Carbon (C) has an electronegativity value of 2.5, while Chlorine (Cl) has a value of 3.0. Since Cl has a higher electronegativity value, the bond will have a polarity as follows: $$\mathrm{C}\delta^+ - \mathrm{Cl}\delta^-$$ (b) \(\mathrm{S}-\mathrm{H}\): Sulfur (S) has an electronegativity value of 2.5, while Hydrogen (H) has a value of 2.1. Since S has a higher electronegativity value, the bond will have a polarity as follows: $$\mathrm{S}\delta^- - \mathrm{H}\delta^+$$ (c) \(\mathrm{C}-\mathrm{S}\): Carbon (C) and Sulfur (S) both have electronegativity values of 2.5. Since they have equal values, there is no polarity in this bond. The bond can be represented as: $$\mathrm{C} - \mathrm{S}$$ (d) \(\mathrm{P}-\mathrm{H}\): Phosphorus (P) has an electronegativity value of 2.1, while Hydrogen (H) has a value of 2.1 as well. Since they have equal values, there is no polarity in this bond. The bond can be represented as: $$\mathrm{P} - \mathrm{H}$$

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