Chapter 10: Problem 15
Make a new bond between a nucleophile and an electrophile. Reaction of the
\(3^{7}\) carbocation (an electrophile) with bromide ion (a nucleophile) gives
the alkyl halide.
Chapter 10: Problem 15
Make a new bond between a nucleophile and an electrophile. Reaction of the
\(3^{7}\) carbocation (an electrophile) with bromide ion (a nucleophile) gives
the alkyl halide.
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Get started for freePrimary alcohols are oxidized by aqueous \(\mathrm{H}_{2}\) CrO \(\mathrm{O}_{4}\) to give carboxylic acids in a process that involves initial aldehyde formation, followed by conversion to an aldehyde hydirate that is further cxidized to the casboxylic acid.
From each pair of compounds, select the one that is more soluhle in water.
(a) \(\mathrm{CH}_{2} \mathrm{Cl}_{2}\) or \(\mathrm{CH}_{2} \mathrm{OH}\)
(b) \(\mathrm{CH}_{3} \mathrm{CXCH}_{3}\) or \(\mathrm{CH}_{3} \mathrm{CCH}_{3}\)
(c) \(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{Cl}\) or \(\mathrm{NaCl}\)
(d)
It should come zo no surprise that biological systems do not use agents like: potassiam dichromate or the oxides of other transition metals for the oxidation of alicohols to aldehydes and ketones, or for the oxidation of aldehydes to rarbosylic acids. What biological systems use instead is \(\mathrm{NAD}^{*}\), a compound derived from niacin, one of the B coenplex vatamins. Nicotizic acid (Niacin, Vataxnin Li6)
Sinmilarly, thiols are stronger acids than alcohols. Compare, for example, the p \(K\). values of ethanol and ethanethiol in dilute aquecous solution.
Show hos to convert propene to each of these compounds, using any anorganic reagents as necessary: (a) Propane (b) 1,2-Propanedicol (c) 1-Propanol (d) 2-Propanol (e) Propanal (f) Propanone (g) Propanoic acid (h) 1-Hroeno-2-propanod (i) SChloropropene (j) \(1,2,3\)-Trichloropropane (k) 1-Chlaropropaise (1) 2-Chlocopropane (m) 2-Propen-1-al (a) Propenal
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