Chapter 2: Problem 17
Write the molecular formula of each alkane.
(a)
Chapter 2: Problem 17
Write the molecular formula of each alkane.
(a)
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Get started for freeWhich cycloalkanes show cis, trans isomerism? For each that does, draw both isomers.
Following is a chair conformation of cyclohexane with the carbon atoms numbered 1 through \(6 .\) (a) Draw hydrogen atoms that are above the plane of the ring on carbons 1 and 2 and below the plane of the ring on carbon 4 . (b) Which of these hydrogens are equatorial? Which are axial? (c) Draw the alternative chair conformation. Which hydrogens are equatorial? Which are axial? Which are above the plane of the ring? Which are below it?
Each member of the following set of compounds is an alcohol; that is, each
contains an -OH (hydroxyl group, Section 1.3A). Which structural formulas
represent the same compound, and which represent constitutional isomers?
(a)
Following are the alternative chair conformations for trans-1,2-dimethylcyclohexane. (a) Estimate the difference in free energy between these two conformations. (b) Given your value in (a), calculate the percent of each chair present in an equilibrium mixture of the two at \(25^{\circ} \mathrm{C}\).
Complete and balance the following combustion reactions. Assume that each hydrocarbon is converted completely to carbon dioxide and water. (a) Propane \(+\mathrm{O}_{2} \rightarrow\) (b) Octane \(+\mathrm{O}_{2} \rightarrow\) (c) Cyclohexane \(+\mathrm{O}_{2} \rightarrow\) (d) 2-Methylpentane \(+\mathrm{O}_{2} \rightarrow\)
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