Chapter 2: 37P (page 139)
Rank the following species in order of increasing acidity. Explain your reasons for ordering them as you do.
Chapter 2: 37P (page 139)
Rank the following species in order of increasing acidity. Explain your reasons for ordering them as you do.
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Get started for freeThe N-F bond is more polar than N-H bond, but NF3 has smaller dipole moment than NH3. Explain the curious result.
NH3: µ= 1.5 D, NF3: µ= 0.2D
Choose the more acidic member of each pair of isomers, and show why the acid you chose is more acidic.
(a)
Each of these compounds can react as a nucleophile. In each case, use curved arrows to show how the nucleophile would react with the strong electrophile, BF3.
(a)
(b)
(c)
(d)
(CH3)3H
(e)
CH3CH2OH
(f)
(CH3 )2S
Which of the following pure compounds can form hydrogen bonds? Which can form hydrogen bonds with water? Which ones do you expect to be soluble in water?
(a)
(b)
(c)
(d)
(e)
(f)
(g)
(h)
(i)
(j)
(k)
(l)
The C ≡ N triple bond in acetonitrile has a dipole moment of about 3.6Dand a bond length of about 1.16Å. Calculate the amount of charge separation in this bond. How important is the charge separated resonance form in the structure of acetonitrile?
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