Chapter 2: Q32 P (page 138)
Predict which member of each pair is more soluble in water. Explain your prediction.
(a)
(b)
(c)
(d)
(e)
(f)
Short Answer
(a)
(b)
(c)
(d)
(e)
(f)
Chapter 2: Q32 P (page 138)
Predict which member of each pair is more soluble in water. Explain your prediction.
(a)
(b)
(c)
(d)
(e)
(f)
(a)
(b)
(c)
(d)
(e)
(f)
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Get started for freeCompare the relative acidity of 1-molar aqueous solutions of the following acids.
Many naturally occurring compounds contain more than one functional group. Identify the functional groups in the following compounds
Ethyllithium is often used as a base in organic reactions,
(a)Predict the products of the following acid-base reaction,
CH3OH + CH3CH2Li
(b) What is the conjugate acid ofCH3CH2Li ? Would you expectCH3CH2Li to be a strong base or a weak base?
Question: The pKa of ascorbic acid (vitamin C, page 9) is 4.17 , showing that it is lightly more acidic than acetic acid (CH3COOH, pKa = 4.74).
(a)Show four different conjugate bases that would be formed by deprotonation of the four different OH groups in ascorbic acid.
(b) Compare the stabilities of these four conjugate bases, and predict which OH group of ascorbic acid is the most acidic.
(c) Compare the most stable conjugate base of ascorbic acid with the conjugate base of acetic acid, and suggest why these two compounds have similar acidities, even though ascorbic acid lacks the carboxylic acid (COOH) group
Dimethyl ether and ethanol are isomers. Their boiling points are very different, however. Explain why these two compounds have dramatically different boiling points.
CH3-O-CH3 CH3CH2-OH
dimethyl ether, bp -24 °C ethanol, bp 78 °C
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