Circle the functional groups in the following structures. State to which class (or classes) of compounds the structure belongs.

(a)

(b)


(c)

(d)

(e)

(f)

(g)

(h)


(i)

Short Answer

Expert verified

(a) ether

(b) carboxylic acid, alkene

(c) aldehyde, alkene

(d) aromatic hydrocarbon, ketone

(e) ester, alkene

(f) amide

(g) aromatic hydrocarbon, ether, nitrile

(h) amine, ester

(i) alcohol, carboxylic acid, amine

Step by step solution

01

Functional group

A functional group may be defined as an atom or a group of atoms that gives some characteristic properties to a compound.

The compounds containing hydroxy (-OH)functional group are classified as alcohols. Alcohols have the general formulaR-OH, where R =alkyl group.

The functional group is which two alkyl groups are bonded to an oxygen atom are known as ethers. Ethers have the general formulaR-O-R/ , whereR andR/ represent alkyl groups.

The functional group in which carbon atom is bound to three other atoms namely, a single bond to a carbon atom, a double bond to an oxygen atom, and also a single bond to an oxygen atom. The singly bound oxygen atom is bound to another carbon

atom. This type of functional group is known as an ester.

The functional group for both aldehydes and ketones are the carbonyl group (C=O). In a ketone, there are two alkyl groups bonded to the carbonyl group whereas in an aldehyde, there is one alkyl group and one hydrogen atom bonded to the carbonyl group.

The functional group in which carboxyl group,-COOHgroup is present is referred to as carboxylic acid. Carboxylic acids have the general formulaR-COOH or R-CO2H, where R =alkyl group.

Alkylated derivatives of ammonia(NH3) are known as amines.

Acid derivatives resulting from the combination of an acid with ammonia(NH3) or an amine are known as amides.

A compound containing cyano (-CN)group is known as nitrile.

Alkenes are the hydrocarbons which contain carbon-carbon double bond (C=C)as their functional group.

Aromatic hydrocarbons are the benzene derivatives that are represented by a six membered ring containing three double bonds. They are also known as arenes.

02

Classification of compounds

(a)

It can be seen that the two alkyl groups are bonded to an oxygen atom. This type of functional group is known as an ether.

(b)

It can be seen that carboxyl group, -COOH is present. This type of functional group is known as carboxylic acid. Also, it contains carbon-carbon double bond (C=C)which is known as alkene functional group.

(c)

It can be seen that there is one alkyl group and one hydrogen atom bonded to the carbonyl group(C=C) which is known as the aldehyde functional group. Also, it contains carbon-carbon double bond (C=C)which is known as alkene functional group.

(d)

It can be seen that there is benzene derivative containing three double bonds which is known as the aromatic hydrocarbon. Also, it can be seen that there are two alkyl groups bonded to the carbonyl group (C=C)which is known as ketone functional group.

(e)

It can be seen that the carbon atom is bound to three other atoms namely, a single bond to a carbon atom, a double bond toan oxygen atom, and also a single bond to an oxygen atom. The singly bound oxygen atom is bound to another carbon atom. This type of functional group is known as an ester. Also, it contains carbon-carbon double bond (C=C)which is known as alkene functional group.

(f)

It is an acid derivative resulting from thecombination of an acid with an amine. This type of functional group is known as an amide.

(g)

It can be seen that there is benzene derivative containing three double bonds which is known as the aromatic hydrocarbon. Also, it can be seen that the two alkyl groups are bonded to an oxygen atom. This type of functional group is known as an ether. Lastly, cyano(-CN) group is also present and this type of functional group is known as a nitrile.

(h)

It is an alkylated derivatives of ammonia(NH3) . This type of functional group is known as an amine. Again, it can be seen that the carbon atom is bound to three other atoms namely, a single bond to a carbon atom, a double bond to an oxygen atom, and also a single bond to an oxygen atom. The singly bound oxygen atom is bound to another carbon atom. This type of functional group is known as an ester.

(i)

It can be seen that hydroxy (-OH)functional group is present. This type of functional group is known as an alcohol. Also, it can be seen that carboxyl group, -COOH is present. This type of functional group is known as carboxylic acid. Lastly, it is an alkylated derivative of ammonia (NH3)which is known as an amine.

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Most popular questions from this chapter

Question: Circle the functional groups in the following structures. State to which class (or classes) of compounds the structure belongs.

(a)

(b)

(c)

(d)

(e)

(f)

(g)

(h)

(i)

Two isomers of 1,2 Dichloroethene are known. One has dipole moment of 2.4 D; the other has zero dipole moment. Draw the two isomers, and explain why one has zero dipole moment

CHCl=CHCl (1,2 Dichloroethene)

The following compounds can all react as bases.

  1. For each compound, show its conjugate acid. Show any resonance forms if applicable.
  2. Rank the conjugate acids in the order you would predict, from most stable to least stable.
  3. Rank the original compounds in order from strongest base to weakest base.

Ethyllithium is often used as a base in organic reactions,

(a)Predict the products of the following acid-base reaction,

CH3OH + CH3CH2Li

(b) What is the conjugate acid ofCH3CH2Li ? Would you expectCH3CH2Li to be a strong base or a weak base?

The pKa of ascorbic acid (vitamin C, page 9) is 4.17 , showing that it is lightly more acidic than acetic acid (CH3COOH,pKa =4.74) .

(a)Show four different conjugate bases that would be formed by deprotonation of the four different OH groups in ascorbic acid.

(b) Compare the stabilities of these four conjugate bases, and predict which OH group of ascorbic acid is the most acidic.

(c) Compare the most stable conjugate base of ascorbic acid with the conjugate base of acetic acid, and suggest why these two compounds have similar acidities, even though ascorbic acid lacks the carboxylic acid (COOH ) group

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