Chapter 6: Q-6-4P (page 288)
Kepone, aldrin, and chlordane are synthesized from hexachlorocyclopentadiene and other five-membered ring compounds. Show how these three pesticides are composed of two five-membered rings.
Chapter 6: Q-6-4P (page 288)
Kepone, aldrin, and chlordane are synthesized from hexachlorocyclopentadiene and other five-membered ring compounds. Show how these three pesticides are composed of two five-membered rings.
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Get started for freeWhen water is shaken with hexane, the two liquids separate into two phases. Which compound is present in the top phase, and which is present in the bottom phase? When water is shaken with chloroform, a similar two-phase system results. Again, which compound is present in each phase? Explain the difference in the two experiments. What do you expect to happen when water is shaken with ethanol (CH3CH2OH)?
Propose a mechanism involving a hydride shift or alkyl shift for each solvolysis reaction. Explain howeach rearrangement forms a more stable intermediate.
(a)
(b)
(c)
(d)
Give systematic (IUPAC) names for the following compounds.
Draw the structures of the following compounds.
(a)sec-butyl bromide
(b)isobutyl chloride
(c) 1,2-chloro-3-methylpentane
(d) 2,2,2-tribromoethanol
(e) trans-1-bromo-2-methylcyclohexane
(f) methylene bromide
(g) iodoform
(h) 1-bromo-1-isopropylcyclopentane
(i) tert-pentyl bromide
Question: Using cyclohexane as one of your starting materials, show how you would synthesize the following compounds.
b)
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