Chapter 23: Q37P (page 1236)
Give an equation to show the reduction of Tollens reagent by maltose.
Short Answer
The reduction of Tollens reagent by maltose is shown below.
Chapter 23: Q37P (page 1236)
Give an equation to show the reduction of Tollens reagent by maltose.
The reduction of Tollens reagent by maltose is shown below.
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a) Draw D-allose, the C3 epimer of glucose.
b) Draw D-talose, the C2 epimer of D-galactose.
c) Draw D-idose, the C3 epimer of D-talose. Now compare your answers with Figure 23-3.
d) Draw the C4 “epimer” of D-xylose. Notice that this “epimer” is actually an L-series sugar, and we have seen its enantiomer. Give the correct name for this L-series sugar.
Cytosine, uracil and guanine have tautomeric forms with aromatic hydroxyl groups. Draw these tautomeric forms.
Does lactose mutarotate? Is it a reducing sugar? Explain. Draw the two anomeric forms of lactose.
Use fig. 23-3 (the D-family of aldoses) to name the following aldoses.
(a) The C2 epimer of D-xylose
(b) The C3 epimer of D-erythrose
(c) The C3 epimer of D-altros
(d) The enantiomer of D-talose
(e) The C-5 epimer of D-idose
Draw the following monosaccharides, using chair conformations for the pyranoses and Haworth projections for the furanoses.
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