Chapter 21: Q36P-a (page 1129)
Show how you would accomplish the following synthetic transformations. You may use any necessary reagents.
Short Answer
Synthetic transformation for N-ethylbenzamide to benzylethylamine is show as,
Chapter 21: Q36P-a (page 1129)
Show how you would accomplish the following synthetic transformations. You may use any necessary reagents.
Synthetic transformation for N-ethylbenzamide to benzylethylamine is show as,
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Get started for freeExplain this curious result. What does this reaction tell you about the relative reactivity of esters and ketones?
Complete the mechanism for this acid-catalyzed transesterification by drawing out all the individual steps. Draw the important resonance contributors for each resonance stabilized intermediate.
An ether extraction of nutmeg gives large quantities of triolein, a waxy crystalline solid of melting point 57 °C. The IR spectrum of triolein shows a very strong absorption at1735 cm-1 . Basic hydrolysis of triolein gives 1 equivalent of glycerol and 3 equivalents of oleic acid ((9Z)-Octadec-9-enoic acid).
(a) Draw the structure of triolein.
(b) Predict the products formed when triolein is treated with lithium aluminum hydride, followed by aqueous hydrolysis of the aluminum salts.
What characteristics of the phenyl propanoate spectrum rule out an aldehyde or carboxylic acid functional group giving the absorption at 1730 cm-1?
Show how you would synthesize each compound, starting with an ester containing nomore than eight carbon atoms. Any other necessary reagents may be used.
(i). OH-(CH2)8-OH
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