Chapter 20: 58 P-b (page 1038)
Question: Show the products you expect when each compound reacts with NBS with light shining on the reaction.
b)
Short Answer
b)The product formed from the above compound when react with NBS
Chapter 20: 58 P-b (page 1038)
Question: Show the products you expect when each compound reacts with NBS with light shining on the reaction.
b)
b)The product formed from the above compound when react with NBS
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Get started for freeQuestion: A carboxylic acid has two oxygen atoms, each with two nonbonding pairs of electrons.
Question:
Show how you would accomplish the following syntheses. Some of these conversions may require more than one step.
(a) isopentyl alcohol isopentyl acetate (banana oil)
(b) 3-ethylpentanoic acid3-ethylpentanenitrile
(c) isobutylamineN-isobutylformamide
(d) ethyl acetate3-methylpentan-3-ol
(e) cyclohexylamineN-cyclohexylacetamide
(f) bromocyclohexanedicyclohexylmethano
(g)
(h)
Show how you would accomplish the following syntheses efficiently (you may use any necessary reagents).
(a)trans-1-bromobut-2-ene→trans-pent-3-enoic acid (two ways)
(b)hex-3-ene→propanoic acid
(c) but-2-enal→but-2-enoic acid
(d) hexanoic acid→hexanal
(e)
(f)
(g)
(h)
Question:An unknown compound gives a molecular ion of m/z 70 in the mass spectrum. It reacts with semicarbazide hydrochloride to give a crystalline derivative, but it gives a negative Tollens test. The NMR and IR spectra follow. Propose a structure for this compound, and give peak assignments to account for the absorptions in the spectra. Explain why the signal at 1790 cm-1 in the IR spectrum appears at an unusual frequency.
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