Question: Draw the structures of the following compounds.

  1. propanoic acid
  2. phthalic acid
  3. calciumformate
  4. succinic acid
  5. dibromoacetic acid
  6. acetylsalicylate (aspirin)
  7. zincdecanoate (athlete's-foot powder)
  8. potassium benzoate (a food preservative)
  9. potassium fluoroacetate

Short Answer

Expert verified

Answer

a.

b.

c.

d.

e.

f.

g.

h.

i

Step by step solution

01

Structure of compounds

The structure of compounds is drawn by looking at the IUPAC name of the compound.The number of carbon atoms and functional groups attached to them is known from the compound's name.

02

The structure of propanoic acid

a. In propanoic acid, the 'propan' word is used for three carbon-containing compounds, and 'oic acid' means –COOH functional group. So, the structure of propanoic acid is shown as,


Structure of propanoic acid

03

The structure of phthalic acid

b. Phthalic acid is an aromatic compound containing two –COOH functional groups, and the other name for phthalic acid is benzene dicarboxylic acid. The two carboxyl groups are present at the ortho position. The chemical formula for phthalic acid is C6H4 (COOH)2 , and the structure is shown as,


Structure of phthalic acid

04

The structure of calcium formate 

C. Calcium formate is a compound containing calcium salt with a +2 charge and HCO O- (formate ion). So, to balance the charge on both sides, two formate ions are there in calcium formate. The chemical formula for calcium formate is Ca (COOH)2 , and the structure is shown as,

Structure of calcium formate

05

The structure of succinic acid

d. Succinic acid is a compound containing two carboxylic acids, and the chain comprises a total of 4 carbon atoms. The other name for succinic acid is butanedioic acid. The chemical formula for succinic acid is (CH2 )2 (C00H)2 , and the structure is shown as,


Structure of succinic acid

06

The structure of dibromoacetic acid

e. Dibromoacetic acid is a compound in which two bromine atoms replace two hydrogens of the methyl group of acetic acid (CH3 COOH). The chemical formula for dibromoacetic acid is C2H2Br2CO2 , and the structure is shown as,


Structure of dibromoacetic acid

07

The structure of acetylsalicylate (aspirin)

f. Acetylsalicylate (aspirin) is a compound formed by deprotonation of the carboxy group of acetylsalicylic acid. The chemical formula for this compound is C6H4 (CH3 COO)COO- , and the structure is shown as,


Structure of acetylsalicylate (aspirin)

08

The structure of zincdecanoate  

g. Zincdecanoate is a compound containing Zn cation with a +2 charge and decanoate anion (C10H19O2-). So, to balance the charges, two deconate anions are used. The chemical formula for this compound is (C10H19O2-)2 Zn+ , and the structure is shown as,


Structure of zincdecanoate

09

The structure of potassium benzoate

h. Potassium benzoate is a compound containing potassium (K+) cation and benzoate anion (C7H1202-). The charges of both the ions are balanced. The chemical formula for this compound is C7H1202- K+ , and the structure is shown as,

Structure of potassium benzoate

10

The structure of potassium fluoroacetate

I. Potassium fluoroacetate contains potassium (K+) cation and fluoroacetate anion. The fluoroacetate anion is formed when one hydrogen of methyl group of acetate ion is replaced by an F atom (FCH2CO2-). The charges of both the ions are balanced. The chemical formula for this compound is FCH2CO2-K+ , and the structure is shown as,


Structure of potassium fluoroacetate

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Most popular questions from this chapter

Circle the isoprene units in geranial, menthol, camphor, and abietic acid.

Question: Phenols are less acidic than carboxylic acids, with values of around 10. Phenols are deprotonated by (and therefore soluble in) solutions of sodium hydroxide but not by solutions of sodium bicarbonate. Explain how you would use extractions to isolate the three pure compounds from a mixture of p-cresol (p-methylphenol), cyclohexanone, and benzoic acid.

(a)Hydrogen peroxide (HOOH) has a pKa of 11.6, making it roughly 10,000 times as strong an acid as water (pKa = 15.7). Explain why H2O2is a stronger acid than H2O.

(b) In contrast to part (a), peroxyacetic acid (pKa = 8.2) is a much weakeracid than acetic acid (pka = 4.74) . Explain why peroxyacetic acid is a weaker acid than acetic acid.

(c) Peroxyacetic acid (bp = 105° C) has a lower boiling point than acetic acid (bp = 118° C) , even though peroxyacetic acid has a higher molecular weight. Explain why peroxyacetic acid is more volatile than acetic acid.

Question: A carboxylic acid has two oxygen atoms, each with two nonbonding pairs of electrons.

  1. Draw the resonance forms of a carboxylic acid that is protonated on the hydroxy oxygen atom.
  2. Compare the resonance forms with those given previously for an acid protonated on the carbonyl oxygen atom.
  3. Explain why the carbonyl oxygen atom of a carboxylic acid is more basic than the hydroxy oxygen.

Question: Oxidation of a primary alcohol to an aldehyde usually gives some over-oxidation to the carboxylic acid. Assume you have used PCC to oxidize pentan-1-ol to pentanal.

(b). Which of the expected impurities cannot be removed from pentanal by acid-base extractions? How would you remove this impurity?

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