Predict the major form of each compound when it is dissolved in pure water. To do this, you will need to estimate values for the compounds in (a), (b), and (c) based on similar compounds shown in Appendix 4. Values for the compound in (d) are given. Explain the differences, including why the values in part (d) are so different from the others.

Short Answer

Expert verified

(a) The name of the given compound is 2-(4-(aminomethyl) phenyl)acetic acid.There is one group with the COOH group attached to the benzene ring. At the para position, group is present.

Step by step solution

01

About the given compound (a)

(a) The name of the given compound is 2-(4-(aminomethyl) phenyl)acetic acid.There is one group with the COOH group attached to the benzene ring. At the para position, group is present.

02

About the product

The value is 4.7 for acetic acid. The product formation is favorable at equilibrium condition. There will be a difference of 6 value.

03

About the product

There will be the formation of an ion called 2-(4-(ammoniomethyl)phenyl)acetate. In this compound, there are three hydrogens attached to nitrogen and one positive charge on nitrogen. There is one negative charge on the carboxyl group.

04

About the given compound (b)

(b) The value is 4.31 for acetic acid. The product formation is favorable at equilibrium conditions. The formed product is major at equilibrium condition.

05

About the product

There will be the formation of an ion called 2-(4-aminophenyl)acetate. In this compound, there are three hydrogens attached to nitrogen and one positive charge on nitrogen. There is one negative charge on the carboxyl group.

06

About the given compound (c)

(c) The value is 4.2 for benzoic acid. The product formation is favorable at equilibrium conditions. The formed product is major at equilibrium condition.

07

About the product

There will be the formation of an ion called 4-metheyliumylbenzoate, ammonia salt. In this compound, there are three hydrogens attached to nitrogen and one positive charge on nitrogen.

There is one negative charge on the carboxyl group.

08

About the given compound (d)

The value is 4.9 for benzoic acid. The product formation is favorable at equilibrium conditions. The formed product is major at equilibrium condition.

09

About the product

There will be the formation of an ion called 4-ammoniobenzoate. In this compound, there are three hydrogens attached to nitrogen and one positive charge on nitrogen. There is one negative charge on the carboxyl group.

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Most popular questions from this chapter

The 2000 Nobel Prize in Chemistry was awarded for work on polyacetylenes. Acetylene can be polymerized using a Ziegler-Natta catalyst. The cis or trans stereochemistry of the products can be controlled by careful selection and preparation of the catalyst. The resulting polyacetylene is an electrical semiconductor with a metallic appearance. cis-Polyacetylene has a copper color, and trans-polyacetylene is silver.

(a) Draw the structures of cis- and trans-polyacetylene.

(b) Use your structures to show why these polymers conduct electricity.

(c) It is possible to prepare polyacetylene films whose electrical conductivity is anisotropic. That is, the conductivity is higher in some directions than in others. Explain how this unusual behavior is possible.

Show how you would synthesize the following compounds, starting with acetylene and any compounds containing no more than four carbon atoms.

(a)hex-1-yne

(b)hex-2-yne

(c)cis-hex-2-ene

(d)trans-hex-2-ene

(e)1,1-dibromohexane

(f)2,2-dibromohexane

(g)pentanal, CH3CH2CH2CH2CHO

(h)pentan-2-one, CH3-CO-CH 2CH2 CH3

(i) (+/)-3,4-dibromohexane

(j)meso-butan-2,3-diol

(k)2-methylhex-3-yn-2-ol

Question: Suppose you have just synthesized heptanoic acid from heptan-1-ol. The product is contaminated by sodium dichromate, sulfuric acid, heptan-1-ol, and possibly heptanal. Explain how you would use acid-base extractions to purify the heptanoic acid. Use a chart, like that in Figure 20-3, to show where the impurities are at each stage.

Question: Show the products you expect when each compound reacts with NBS with light shining on the reaction.

a)

Question: Draw the structures of the following compounds.

  1. propanoic acid
  2. phthalic acid
  3. calciumformate
  4. succinic acid
  5. dibromoacetic acid
  6. acetylsalicylate (aspirin)
  7. zincdecanoate (athlete's-foot powder)
  8. potassium benzoate (a food preservative)
  9. potassium fluoroacetate
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