Chapter 22: Q71P-d (page 1205)
Show how you would accomplish the following conversions in good yields. You may use any necessary reagents.
Short Answer
A reagent used is witting reagent
Chapter 22: Q71P-d (page 1205)
Show how you would accomplish the following conversions in good yields. You may use any necessary reagents.
A reagent used is witting reagent
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Get started for freeQuestion:Show how you would use an aldol, Claisen, or another type of condensation to make each compound
d.
Show how you would use the acetoacetic ester synthesis to make the following compounds
Write equations showing the expected products of the following enamine alkylation and acylation reactions. Then give the final products expected after hydrolysis of the iminium salts.
(a) pyrrolidine enamine of pentan-3-one + allyl chloride
(b) pyrrolidine enamine of acetophenone + butanoyl chloride
(c) piperidine enamine of cyclopentanone + methyl iodide
(d) piperidine enamine of cyclopentanone + methyl vinyl ketone
Show how you would use the acetoacetic ester synthesis to make the following compounds
Some (but not all) of the following keto esters can be formed by Dieckmann condensations. Determine which ones are possible, and draw the starting diesters.
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