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Chapter 14: Q30P (page 746)

Give common names for the following compounds

Short Answer

Expert verified

Answer

(a

(e

Step by step solution

01

Ethoxy

The name of the following compound is 2-ethoxypropane. Second position of propane ethoxy group is present.

02

Proproxy

The name of the following compound is 2-methyl-2-propoxypropane. In second position methyl and propoxy group are present in propane

03

anisole

This is anisole. Methoxy group is present in phenyl, it is anisole

04

Ethane

The name of the compound is (chloromethoxy) ethane. Chloromethoxy group is present in ethane

05

chair cyclohexane

The name of the compound is (1R,2S)-2-methoxycyclohex-1-ol. In cyclohexane ring OH is present in upside axial position and the bmethoxy group is present in equatorial position

(e

06

methoxycyclohexane

The name of the compound is methoxycyclohexane. Methoxy group is present in cyclohexane ring carb on.

07

trimethyloxirane

The name of the compound is (S)-2,2,3-trimethyloxirane. In cyclopropane ring second position is occupied by one methyl and third position is occupied by two methyl groups

08

allyloxy

The name of the compound is (allyoxy)cyclopropane. Allyoxy group is present in cyclopropane.

09

heptanes

The name of the compound is 7-oxabicyclo[4.1.0]heptanes. The bicycle compound with nomenclature

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Most popular questions from this chapter

An acid-catalyzed reaction was carried out using methyl cellosolve (2-methoxyethanol) as the solvent. When the 2-methoxyethanol was redistilled, a higher-boiling point fraction (bp 162oC) was also recovered. The mass spectrum of this fraction showed the molecular weight to be 134. The IR and NMR spectrum are shown here. Determine the structure for this compound and propose a mechanism for its formation.

Propose a fragmentation to account for each numbered peak in the mass spectrum of n-butyl isopropyl ether.

Question. The following reaction resembles the acid-catalyzed cyclization of squalene oxide. Propose a mechanism for this reaction.

Show how the following ethers might be synthesized using (1) alkoxymercuration-demercuration and (2) the Williamson synthesis. (When one of these methods cannot be used for the given ether, point out why it will not work.)

  1. 2-methoxybutane
  2. Ethyl cyclohexyl ether
  3. 1-methoxy-2-methylcyclopentane
  4. 1-methoxy-1-methylcyclopentane
  5. 1-isopropoxy-1-methylcyclopentane
  6. Tert-butyl phenyl ether

There are two ways of making 2-ethoxyoctane from octan-2-ol using the Williamson ether synthesis. When pure (-) -octan-2-ol of specific rotation -8.240is treated with sodium metal and then ethyl iodide, the product is 2-ethoxyoctane with a specific rotation of -15.60. When pure (-) -octan-2-ol is treated with tosyl chloride and pyridine and then with sodium ethoxide, the product is also 2-ethoxyoctane. Predict the rotation of the 2-ethoxyoctane made using the tosylation/sodium ethoxide procedure, and propose a detailed mechanism to support your prediction.

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